購物車 
-
pNNP
- names：
4-nitrophenyl dihydrogen phosphate
- CAS號：
330-13-2
MDL Number： - MF(分子式)： C6H6NO6P MW(分子量)： 219.08
- EINECS: Reaxys Number:
- Pubchem ID: Brand:BIOFOUNT
| 貨品編碼 | 規格 | 純度 | 價格 (￥) | 現價(￥) | 特價(￥) | 庫存描述 | 數量 | 總計 (￥) |
|---|
| 中文別名 | 4-nitrophenyl dihydrogen phosphate |
| 英文別名 | pNNP; p-NNP; p NNP; p-Nitrophenyl phosphate; |
| CAS號 | 330-13-2 |
| Inchi | InChI=1S/C6H6NO6P/c8-7(9)5-1-3-6(4-2-5)13-14(10,11)12/h1-4H,(H2,10,11,12) |
| InchiKey | XZKIHKMTEMTJQX-UHFFFAOYSA-N |
| 分子式 Formula | C6H6NO6P |
| 分子量 Molecular Weight | 219.08 |
| 溶解度Solubility | |
| 性狀 | Solid powder |
| 儲藏條件 Storage conditions | Dry, dark and store at 0-4℃ for short term (days to weeks) or -20℃ for long term (Store correctly 2-3years). |
| 產品說明 | pNNP(CAS:330-13-2):僅限應用于工業或者科學研究過程中非醫療目的，不應用于人類或動物的臨床診斷以及治過程療，該產品非藥用，非食用。 |
| Introduction | pNNP is used as a substrate instead of phosphorylated proteins in the PP2C assay. |
| Application1 | |
| Application2 | |
| Application3 |
| [1]Demmans KZ, Seo CSG, Lough AJ, Morris RH. From imine to amine: an unexpected left turn. Cis-β iron(ii) PNNP' precatalysts for the asymmetric transfer hydrogenation of acetophenone. Chem Sci. 2017 Sep 1;8(9):6531-654[1]doi: 10.1039/c7sc02558k. Epub 2017 Jul 14. PubMed PMID: 28989679; PubMed Central PMCID: PMC5627452. |
| [2]Li YY, Yu SL, Shen WY, Gao JX. Iron-, Cobalt-, and Nickel-Catalyzed Asymmetric Transfer Hydrogenation and Asymmetric Hydrogenation of Ketones. Acc Chem Res. 2015 Sep 15;48(9):2587-98. doi: 10.1021/acs.accounts.5b00043. Epub 2015 Aug 24. PubMed PMID: 26301426. |
| [3] Kumar S, Mani G, Dutta D, Mishra S. Structural diversity of copper(I) complexes formed by pyrrole- and dipyrrolylmethane-based diphosphine ligands with cu-X···HN hydrogen bonds. Inorg Chem. 2014 Jan 21;53(2):700-9. doi: 10.1021/ic402253y. Epub 2014 Jan 3. PubMed PMID: 24392950. |
| [4] Kumar S, Mani G, Mondal S, Chattaraj PK. Pyrrole-based new diphosphines: Pd and Ni complexes bearing the PNP pincer ligand. Inorg Chem. 2012 Nov 19;51(22):12527-39. doi: 10.1021/ic301967r. Epub 2012 Nov 8. PubMed PMID: 23137009. |
| [5] Mikhailine AA, Maishan MI, Morris RH. Asymmetric transfer hydrogenation of ketimines using well-defined iron(II)-based precatalysts containing a PNNP ligand. Org Lett. 2012 Sep 7;14(17):4638-41. doi: 10.1021/ol302079q. Epub 2012 Aug 27. PubMed PMID: 22924839. |
6: Mikhailine AA, Maishan MI, Lough AJ, Morris RH. The mechanism of efficient asymmetric transfer hydrogenation of acetophenone using an iron(II) complex containing an (S,S)-Ph2PCH2CH═NCHPhCHPhN═CHCH2PPh2 ligand: partial ligand reduction is the key. J Am Chem Soc. 2012 Jul 25;134(29):12266-80. doi: 10.1021/ja304814s. Epub 2012 Jul 13. PubMed PMID: 22793266.7: Sonnenberg JF, Coombs N, Dube PA, Morris RH. Iron nanoparticles catalyzing the asymmetric transfer hydrogenation of ketones. J Am Chem Soc. 2012 Apr 4;134(13):5893-9. doi: 10.1021/ja211658t. Epub 2012 Mar 26. PubMed PMID: 22448656.8: Schotes C, Althaus M, Aardoom R, Mezzetti A. Asymmetric Diels-Alder and Ficini reactions with alkylidene β-ketoesters catalyzed by chiral ruthenium PNNP complexes: mechanistic insight. J Am Chem Soc. 2012 Jan 18;134(2):1331-43. doi: 10.1021/ja210372u. Epub 2012 Jan 6. PubMed PMID: 22191539.9: Schotes C, Mezzetti A. Enantioselective Diels-Alder reactions of unsaturated beta-ketoesters catalyzed by chiral ruthenium PNNP complexes. Chimia (Aarau). 2011;65(4):231-4. PubMed PMID: 21678768.10: Lagaditis PO, Lough AJ, Morris RH. Low-valent ene-amido iron complexes for the asymmetric transfer hydrogenation of acetophenone without base. J Am Chem Soc. 2011 Jun 29;133(25):9662-5. doi: 10.1021/ja202375y. Epub 2011 Jun 7. PubMed PMID: 21627152.1
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